Search results for "SbH3 molecule"

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Vibrational modes of the stibine molecule

2005

International audience; In this paper, we use the algebraic approach to describe the vibrational modes of stibine molecule (of C3v molecular symmetry group) up to 21 quanta. As the stibine molecule exhibits stretch-bend resonances, we build an algebraic pyramidal coupling operator between stretching modes and bending modes adapted to this molecule. The standard deviation associated to the fit of the vibrational levels is 1.75 cm-1.

High excited levels[ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph]StibineAlgebraic approachVibrational modes01 natural sciencesMolecular physicsHot bandchemistry.chemical_compound[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]0103 physical sciencesMolecular symmetryMoleculeSbH3 moleculePhysics::Chemical PhysicsPhysical and Theoretical Chemistry010306 general physicsSpectroscopyCouplingPhysicsQuantitative Biology::Biomolecules010304 chemical physicsGroup (mathematics)Operator (physics)Atomic and Molecular Physics and OpticschemistryMolecular vibrationJournal of Molecular Spectroscopy

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